Browse our full range of workplace health and safety products and services. Classes Azides. Depending on the classification of the dangerous good, one or more of the following safety marks may be required on a small means of containment: See Figure 2 for an example of dangerous goods safety marks on a small means of containment such as a package. Always checkwith Transport Canada andtheTDG Act and Regulationstoensure compliance. colour used for the safety mark (e.g., orange, red, blue). It would be shipped as "UN 2809, MERCURY, 8(6.1)" and assigned to Packing Group II. SAFETY DATA SHEET - Fisher Sci Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. Flammable Liquids 4. We expect this update to take about an hour. WebIn 2007 Mercury Marine began selling its Zeus drive system. As Marine Pollutants Only: Appendix E: Schedule 2 - List of Dangerous Goods, 6 Registration, Approvals and Certification, 8 Manufacture and Modification of Tank Cars and Ton Containers for Transport of Dangerous Goods, 9 Qualifications and Maintenance of Tank Cars and Ton Containers, 10 Selection and Use of Containers for the Handling, Offering for Transport, or Transporting of Dangerous Goods by Rail, 11 Provisions for the One Time Movement of Non-Conforming Containers Presenting Low Safety Risks, Appendix A: Procedure - Liquefied Petroleum Gas Tank Car Emission Standard, Appendix B: Procedure - Anhydrous Ammonia Tank Car Emission Standard, Appendix C: Procedures for Tank-Head Puncture-Resistance Testing, Appendix D: Procedures for Simulated Pool-Fire and Torch-Fire Testing, Appendix E: Schedule 1 - Special Provisions, transportation-related measures and guidance, Methane, compressed or Natural gas, compressed, with high methane content, Methane, refrigerated liquid or natural gas, refrigerated liquid, with high methane content, Methylacetylene and propadiene mixture, stabilized, Dangerous Goods of Class2.1, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 35% but not more than 50% ammonia, Dangerous Goods of Class2.2, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 50% ammonia, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone B, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone C, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone D, Dinitrogen tetroxide, or Nitrogen dioxide, Ethylene oxide or Ethylene oxide, with nitrogen, Sulphur dioxide, liquefied or Sulphur dioxide, Dangerous Goods of Class2.3, not listed above, Dimethylhydrazine, symmetrical or 1,2-Dimethylhydrazine, Organochlorine pesticide, liquid, flammable, toxic, flash point less than 23C (73F), Petroleum sour crude oil, flammable, toxic, Dangerous Goods of Class 3, Packing Group I, not listed above, Ethanol and gasoline mixture, with more than 10 percent ethanol, Organochlorine pesticide, liquid, flammable, toxic, flashpoint less than 23C (73F), Dangerous Goods of Class 3, Packing Group II, not listed above, Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5C (141F), at or above its flashpoint, Dangerous Goods of Class 3, Packing Group III, not listed above, Dangerous Goods of Class4.1, Packing Group I. If the product's name is listed in Schedule 1 or you located it by using the listed UN Number in Schedule 3, use the shipping name and its corresponding data (UN number, class, packing group/category) from that row. This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. Generally, if the shipment includes dangerous goods in Class 7, Radioactive Materials, then two labels are required on the small means of containment. Setup. Mercury Marine Regs. TDG "Special Case and Special Provision Exemptions, NITROSTARCH, WETTED with not less than 20% water, by mass, ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Yes. what is subsidiary class for mercury - Fashion Inspiration and What is its predominant hazard substance and primary hazard? Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. Column 6 Special Provisions Leave the safety marks on a large means of containment until the means of containment is cleaned or purged. No. Hazard class placards are required when the dangerous goods are: Hazard class placards are not required or are optional when only the following dangerous goods (one or more) are present in the shipment: Examples are available from the TDG Directorates FAQ on Part 4 under the question Can you explain the current placarding requirements?. %PDF-1.5 % If two or more dangerous goods have different UN numbers but are identified by the same placard or placards, the placard is required to be displayed only once on each side and on each end of a large means of containment regardless of how many products in the large means of containment have that class (primary or subsidiary) [See Section 4.15 in the TDG Regulations]. There are other considerations for some special dangerous goods, for which additional description words shall be added. Corrosives 9. Mercury and its compounds. %%EOF (6) For transportation by aircraft, the total net mass per package, must be shown unless a gross mass is indicated in Columns (9A) or (9B) of the 172.101 table in which case the total gross mass per package must be shown; or, for Class 7 materials, the quantity of radioactive material must be shown by activity. They also need to be included in Dangerous Goods Declaration and the section 14 of Safety Data Sheets. In this article, we will share with you some rules you need to follow when choosing UN numbers and proper shipping names. a person capable of understanding the nature of the dangerous good (e.g., manufacturer's professional employees such as a chemical engineer, chemist, scientist, etc. (contains Xylene and Benzene), 3, II. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers Placards are not required or are optional for some dangerous goods when the gross quantity of the dangerous goods is 500 kg or less. Only required when a marine pollutant is being transported in a means of containment on a vessel. UN 3506: Mercury contained in manufactured articles - Substance WebClassifying Substances That Are Included in More Than One Class or Packing Group. S.C. Code Regs. They are preferred in the following order: If you cannot find a good match in 1, you move to 2, 3 and 4 by order. (gasoline). Nitrites and their mixtures. Note 4: As the dangerous good is not identified with UN3373, the Category B mark is not required. See the example below. Sodium dithionite or Sodium hydrosulphite, Sodium sulphide, anhydrous or Sodium sulphide, with less than 30% water of crystallization, Dangerous Goods of Class4.2, Packing Group II, not listed above, Fibres or Fabrics, animal or vegetable or synthetic, n.o.s., with oil, Iron oxide, spent or Iron sponge, spent, obtained from hydrocarbon gas purification, Seed cake, with more than 1.5% oil and not more than 11% moisture, Seed cake, with not more than 1.5% oil and not more than 11% moisture. If the dangerous goods are radioactive, the consignor must use the classification determined by the Canadian Nuclear Safety Commission. You need to choose a UN number (usually, 4 digits) and a proper shipping name from Dangerous Goods List that can most accurately describe your dangerous goods. Explosives 2. How do I determine the shipping name when there are several possible shipping names? When shipping marine pollutants by sea, the proper shipping name shall be be supplemented with the technical name of the marine pollutant. a document that explains how the dangerous goods were classified. White asbestos (chrysotile, actinolite, anthophyllite, tremolite), Dangerous Goods of Class9, Packing Group III, Liquids, not listed above, Dangerous Goods of Class9, Packing GroupIII, Solids, not listed above. If you are a consultant, you may get yourself listed in CSP business directory (free) or Abbreviations may be used for indicating packaging types (for example, cyl. for cylinder) provided the abbreviations are commonly accepted and recognizable. entries are assigned with special provisions 274 or 318 (see column 6 in the example below). CHLORINE DIOXIDE is an example of a product that is forbidden by all routes of transportation as indicated in Schedule 3 with an entry of Forbidden in Column 2 - Hazard Class. You may experience longer than usual wait times or partial service interruptions. Other requirements may be listed in other sections, regulations, Codes, or Acts that are not listed in this table. Determine the other classification elements (i.e., hazard class, packing group, etc.). If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. Shipping Name and Description This column gives the shipping names for dangerous goods in alphabetical order within each primary class and within each packing group. You can 1303 0 obj <>stream NOTE: See further belowin the table for placard requirement when the hazard class is 1.1, 1.2, 1.3, 1.4 or 1.5 are above a certain threshold of gross mass/number of articles. The subsidiary class is the other class that further identifies the hazards of the dangerous goods. [1] (iii) The following are excepted from the requirements of paragraph (a)(5) of this section: (A) Bulk packages, provided some indication of the total quantity is shown, for example, 1 cargo tank or 2 IBCs., (B) Cylinders, provided some indication of the total quantity is shown, for example, 10 cylinders.. If you use UN 3077 or UN 3082, the proper shipping name shall also be supplemented with technical names. The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. Note: The information below is provided as guidance only. Packing Group This column gives the packing groups of the dangerous goods. The classification or shipping description is reported in the following order as per Part 3.5: (ii) the shipping name and, immediately after the shipping name unless it is already part of it, (a) for dangerous goods that are subject to special provision 16, the technical name, in parentheses, of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods, and. When the dangerous goods safety marks are, primary class label and each subsidiary class label for each of the dangerous goods, as well as the shipping name and UN number, must be displayed on the overpack, the word overpack is required on at least one side for overpacks with capacity less than 1.8 m3 (64 cubic feet), the words overpack on at least two opposite, required to display subsidiary hazard class placard. Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. It can also negatively affect reproductive health. :), How to Assign UN Packing Group for Dangerous Goods. Are there other requirements for labels on a small means of containment? What are the general requirements for all dangerous goods safety marks? Class 3 Packing Group III. The Proper Shipping Name must be preceded by the word "WASTE"; Solid transported in a molten state: The solution or mixture is mentioned by name in the Dangerous Goods List; The name mentioned only applies to the pure substance; The hazard class or division, subsidiary risk, packing group or physical state of the mixture or solution is different from that of the substance mentioned; The hazard characteristics and properties of the mixture require different emergency response measures; Is it a pure substance or well-defined mixture (by use) or well-defined article? Also, regardless of the quantity of dangerous goods on board, the primary class placard for each of the dangerous goods in a large means of containment must be displayed on each side and on each end of the large means of containment or means of transport. WebProduct Name Mercury(II) sulfate Cat No. See Section 4.16(2) of Part 4 in the TDG Regulations. I, II or III) assigned to the substance or article. See Section 4.23 of Part 4 in the TDG Regulations. For example: the mixture is liquid and homogeneous and the ingredients will not separate (e.g., no visible solids or two different phases such as you would observe when oil and water are mixed). See Section 2.4. Where or how do I find the above information? Basic Information about Mercury The classes in which the dangerous goods are included are ranked in order of precedence in accordance with Section 2.8 to determine the primary class and the potential subsidiary class or classes; The potential PG is United Nations - UNECE Used to display the UN number on a large means of containment (greater than 450 L) when the UN number is not included in the hazard class placard. Mixed Loads: dangerous good whose gross mass is 1000 kg or less, and there are at least two different dangerous goods, and the dangerous goods are contained in at least two small means of containment inside a large means of containment. WebA subsidiary class placard is required to be displayed on a large means of containment for dangerous goods that requires an emergency response assistance plan (ERAP) if they Radioactive 8. ;imX'1r9-Ttomh1!u~cSyK,v=d+2Cl>AmY\t%v|a&H%dl>; CbtgspL4nj(|c24O?DY_L[;!/aw=yAcC)fMZEnti ]~Mal};jv|y{D}odxh*ap-UDw,EY"h7!G07znrn83Qa=Xre:NWMg]3|u`gho7Ay0Cgh!7tf16+OIXe"m>GNkhhu&.7f{,M` =WaJ`I{W2O_eBX;96$ljWt8 The labelling requirements for an overpack depend on whether the labels can be seen through the overpack. Make sure the appropriate labels (TDG or Workplace Hazardous Materials Information System (WHMIS) are used in the workplace as required. 64-23-14 - 64-23-14 - Transportation of Radioactive Material. Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury endobj Solids containing flammable liquid, n.o.s. The three forms WebMercury Marineis a marine enginedivision of Brunswick Corporationheadquartered in Fond du Lac, Wisconsin. A label is used for a small means of containment whose capacity is 450 L or less. However, the safety mark requirements for large means of containment with a capacity of greater than 450 L but less than or equal to 3000 L (i.e., an intermediate bulk container) are: Placards are not required for overpacks as the definition and description for an overpack does not include large means of containment. ), 2. Please also see the following documents in this series: The consignor is responsible for determining the classification of dangerous goods. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. Note that the, classification (primary and subsidiary hazard classes), whether or not they are shipped under a TDG exemption, Label for the primary hazard class for each dangerous good in the package, Label for the subsidiary hazard class (if any) for each dangerous good in the package, Shipping name and technical name when required in Special Provision 16 in Schedule 2 of the TDG Regulations. Where the kits contain only liquids, or solids and liquids, the net mass of liquids within the kits is to be calculated on a 1 to 1 basis, i.e., 1 L (0.3 gallons) equals 1 kg (2.2 pounds); (iii) For dangerous goods in machinery or apparatus, the individual total quantities or an estimate of the individual total quantities of dangerous goods in solid, liquid or gaseous state, contained in the article must be shown; (iv) For dangerous goods transported in a salvage packaging, an estimate of the quantity of dangerous goods per package must be shown; (v) For cylinders, total quantity may be indicated by the number of cylinders, for example, 10 cylinders;, (vi) For items where No Limit is shown in Column (9A) or (9B) of the 172.101 table, the quantity shown must be the net mass or volume of the material. See Section 1.17 in the TDG Regulations. Scheduled maintenance - Thursday, July 12 at 5:00 PM (e) Except for those materials in the UN Recommendations, the ICAO Technical Instructions, or the IMDG Code (IBR, see 171.7 of this subchapter), a material that is not a hazardous material according to this subchapter may not be offered for transportation or transported when its description on a shipping paper includes a hazard class or an identification number specified in the 172.101 Table. Code. They are substances that are identified as Marine pollutants in the IMDG Code Index or substances that satisfy the GHS classification criteria for Hazardous to Aquatic Environment Acute 1, Chronic 1, or Chronic 2. TN Rules and Regs. NOTE: The table below is for guidance purposes only. We expect this update to take about an hour. For information on COVID-19 updates, please visit Canada.ca/coronavirus. Product mixture that consists of multiple dangerous goods: If the shipping name is not a specific name, then the technical name of the most dangerous substance needs to be provided in brackets as required in Special Provision 16 in Schedule 2. As such, the mixture would be assigned the shipping name FLAMMABLE LIQUID, N.O.S.. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. Dangerous goods in large means of containment (greater than 450 L) that are transported at: This sign must be displayed on each side and on each end of the large means of containment (i.e., total of 4 signs) next to each primary class placard for the dangerous goods or, if there is a subsidiary class placard, next to the subsidiary class placard. sponsor this page to leave your contact info on this page.. Are there any exemptions for placards? Special provisions are specified in Column 5 of Schedule 1. View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. Primary Class This column gives the primary class of the dangerous goods. Admin. If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. Products and Column 4 Subsidiary Risk(s) Contains the class number(s) of any subsidiary risk(s). CCOHS: Transportation of Dangerous Goods (TDG) Services Main Page. In response, we have issued some transportation-related measures and guidance. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. However, if the product's name is not listed in Schedule 1 or 3, then the product must be tested at a laboratory. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. Classification is defined in Part 1 of the TDG Regulations as: classification means, for dangerous goods, as applicable, the shipping name, the primary class, the compatibility group, the subsidiary class, the UN number, the packing group, and the infectious substance category.. Subscribe to Free Newsletter Transportation of Dangerous Goods (TDG) - Dangerous Goods Safety Marks (Road), All Mercury is a naturally-occurring chemical element found in rock in the earth's crust, including in deposits of coal. WebIf a type 3 vessel carrying Class 1 DG on board would staying over-night at the WDGA, notification in writing to the Dangerous Goods Unit of the Marine Department will need to be given. There are 4 types of entries consisting of UN numbers and proper shipping names in the Dangerous Goods List. (UN3291). (b) Except as provided in this subpart, the basic description specified in paragraphs (a)(1), (2), (3), and (4) of this section must be shown in sequence with no additional information interspersed.